N/P-based Sterically Demanding Ligands: Synthesis, Reactivity and Catalysis
Publication Date
July 17, 2019
Creator
Abstract
This thesis details aims at forming low-coordinate metal complexes, stabilised by N-based ligands, with significant focus on carbazole based systems. The sysnthesis of ligands containing these moieties is first targeted, giving a detailed explanation of how differing synthetic pathways that allow modifications to the central carbazole core, in turn allow the formation of stable low-coordinate metal centres. Stabilised metal centres derived from these studies, have been found useful in the dehydrogenation of dimethylamine-borane adducts. While also suitable in the selective anti-Markovnikov hydrophosphination of activated alkenes.
Item Type
ethesis
Thesis Type
PhD
Supervisors
Subjects (LC)
Associated Schools / Departments
School of Chemistry
eprints ID
56541
UoN Repository URI
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Name
PhD Thesis Roberto Nolla Saltiel.pdf
Type
Full-text
Description
Examined
Size
9.21 MB
Format
Adobe PDF
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