Supramolecular heterostructures formed by sequential epitaxial deposition of two-dimensional hydrogen-bonded arrays
Publication Date
May 16, 2017
Description
Supramolecular heterostructures are formed by growing sequential layers of bi- and mono-component two-dimensional molecular arrays stabilized by hydrogen bonding. The heterostructures are formed on hexagonal boron nitride by depositing cyanuric acid/melamine (CA.M) followed by terephthalic acid (TPA) or trimesic acid (TMA) and imaged using atomic force microscopy under ambient conditions with resolution approaching 0.1 nm. A clear epitaxial arrangement is observed between these layers having intrinsically distinct symmetries and lattice constants, which for TMA/CA.M corresponds to a (root3 x root3)R30o phase, while TPA forms rows with a molecular separation that matches the CA.M period. Structures calculated using classical molecular dynamics are in excellent agreement with the orientation, registry and dimensions of the epitaxial layers. Calculations confirm that van der Waals interactions provide the dominant contribution to the adsorption energy and registry of the layers.
Coverage (Spatial):
United Kingdom, Nottingham
Coverage (Coordinates):
52.9414090, -1.1912337
Collection dates:
2014-2017
Subjects
Subjects (JACS)
Subjects (LC)
Divisions
University of Nottingham, UK Campus::Faculty of Science::School of Physics and Astronomy
Data type
raw atomic force microscopy images
Funders
Leverhulme Trust
ERC Consolidator Grant
Grant Number
EP/N033906/1
RPG-2016-104
Data collection method
Cypher Atomic Force Microscope, tapping mode, contact mode
Resource languages
English
Publisher
The University of Nottingham
Date Issued
May 16, 2017
File(s)![Thumbnail Image]()
Name
archive.zip
Size
204.94 MB
Format
Unknown
Checksum (MD5)
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