Raw data for new compounds described in the paper: "Enantioselective nickel-catalyzed arylative intramolecular 1,4-allylations"
Publication Date
May 14, 2018
Creators
Description
Raw data for new compounds described in the paper: "Enantioselective nickel-catalyzed arylative intramolecular 1,4-allylations"
The enantioselective nickel-catalyzed desymmetrization of allenyl cyclohexa-2,5-dienones by reaction with arylboronic acids is described. Nickel-catalyzed arylation of the allene gives allylnickel species, which undergo cyclization by 1,4-allylation to produce hexahydroindol-5-ones and hexahydrofuran-5-ones with three contiguous stereocenters in high diastereo- and enantioselectivities.
Associate publ. DOI
Subjects (LCSH)
Subjects
Subjects (JACS)
Subjects (LC)
Divisions
University of Nottingham, UK Campus::Faculty of Science::School of Chemistry
Data type
IR, NMR, mass spectrometry, and HPLC data
Funders
Funders
University of Nottingham
GlaxoSmithKline
Data collection method
Using IR, NMR, and mass spectrometers, and HPLC machines
Resource languages
English
Publisher
Royal Society of Chemistry
Date Issued
May 14, 2018
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HWL_Nickel-catalyzed intramolecular 1,4-allylations_raw data.zip
Size
368.62 MB
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Unknown
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254b76d866cd96577ce73b8a40690077