Raw data for new compounds described in the paper: "Remote Nucleophilic Allylation by Allylrhodium Chain Walking"
Publication Date
July 23, 2018
Creators
Description
Raw data for new compounds described in the paper: "Remote Nucleophilic Allylation by Allylrhodium Chain Walking". Metal migration through a carbon chain is a versatile method for achieving remote functionalization. However, almost all known examples involve the overall net migration of alkylmetal species. Here, we report that allylrhodium species obtained from hydrorhodation of 1,3-dienes undergo chain walking toward esters, amides, or (hetero)arenes over distances of up to eight ethylene units. The final, more highly conjugated allylrhodium species undergo nucleophilic allylation with aldehydes and an imine to give Z-homoallylic alcohols and amines, respectively.
Associate publ. DOI
Subjects (LCSH)
Subjects
Subjects (JACS)
Subjects (LC)
Divisions
University of Nottingham, UK Campus::Faculty of Science::School of Chemistry
Data type
IR, NMR, and mass spectrometry data
Funders
The Basque Country Government
Leverhulme Trust
GlaxoSmithKline
Grant Number
EP/M50810X/1 and EP/K504348/1 and RPG-2016-341
Data collection method
Using IR, NMR, and mass spectrometers
Resource languages
English
Publisher
The University of Nottingham
Date Issued
July 23, 2018
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Name
Raw data.zip
Size
1.02 GB
Format
Unknown
Checksum (MD5)
77a12d2aec72658f10f32c3c19a4c5fe