An on-surface reaction confined within a porous molecular template
Publication Date
April 25, 2019
Creators
Description
On-surface reactions based on metal-catalysed Ullmann coupling have been successfully employed to synthesise a wide variety of covalently coupled structures. Substrate chemistry and topology are both known to effect the progression of an on-surface reaction; offering routes to control efficiency and selectivity. Here, we detail ultra-high vacuum scanning probe microscopy experiments showing that templating a catalytically active surface, via a supramolecular template, influences the reaction pathway of an on-surface Ullmann-type coupling reaction by inhibiting one potential intermediate structure and stabilising another.
Related resources
Subjects
Subjects (JACS)
Subjects (LC)
Divisions
University of Nottingham, UK Campus::Faculty of Science::School of Physics and Astronomy
University of Nottingham, UK Campus::Faculty of Science::School of Chemistry
Data type
Scanning tunnelling microscopy images (STM)
Funders
People Programme (Marie Curie Actions) of the European Union's Seventh Framework Programme
Grant Number
623992-TOPCHEM
EPSRC Doctoral Training Grant
Data collection method
Scanning Tunelling Microscopy (STM): Omicron LT- UHV STM/AFM system + Omicron STM-1 RT-UHV system
Resource languages
English
Publisher
The University of Nottingham
Date Issued
April 25, 2019
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Name
Judd_et_al_Chem_Eur_J_Data.zip
Size
87.86 MB
Format
Unknown
Checksum (MD5)
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